https://nova.newcastle.edu.au/vital/access/ /manager/Index en-au 5 https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:23117 Sat 24 Mar 2018 07:15:31 AEDT ]]> https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:23115 (v) or D₂O_(v) respectively, the rate of reaction decreases significantly in the presence of a high concentration of water vapour (ca 12,000 ppm) but the overall rate ratio, CH₄ / H₂O_(v) vs CD₄ / D₂O_(v) increases only slightly, to 3.2 ±0.6. This suggests that the effect of water vapour on the reaction rate is attributable to an equilibrium isotope effect (EIE) but under all reaction conditions studied at 270 °C, the rate limiting step involves methane activation.]]> Sat 24 Mar 2018 07:15:30 AEDT ]]> https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:23116 Sat 24 Mar 2018 07:15:30 AEDT ]]> https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:23114 Sat 24 Mar 2018 07:15:30 AEDT ]]>